自動SPE膜萃取裝置

Biotage Horizon 5000
Automated SPE Disk System

Horizon公司設計全自動化的SPE-DEX®5000全自動固相萃取膜系統，係採用SPE萃取膜進行萃取。固相萃取(Solid Phase Extraction,SPE)是液體樣品通過含吸附劑顆粒的萃取膜或萃取管柱的萃取過程，分析物先從液體樣品中被吸附分離出來至吸附劑上，然後經由一系列溶劑把分析物從吸附劑上脫附下來。固相萃取能夠顯著提高萃取效率，排除人為干擾因素，從而保證結果的一致性和準確性，使得原本繁瑣、耗時的有機樣品前處理得以簡化、快速完成，並且提高回收率。與傳統的液液萃取相比，SPE萃取膜技術具有強大優勢，且日益取代傳統的液液與手動SPE管柱萃取技術。

技術簡介

SPE固相萃取膜相較於Cartridge管柱的優點：

不需流量控制(100 – 200 ml / min)
高動力吸附
前處理時間短，只需數分鐘
樣品處理體積大，可高達8公升
可處理污濁樣品
因保留帶在萃取膜上面，固相萃取膜不會發生「破出」現象，在萃取水樣時已逐漸替代Cartrige萃取管柱

萃取水樣的首選─SPE固相萃取膜

SPE萃取膜由多孔網狀聚四氟乙烯等高分子材料或玻璃纖維和各種化學鍵合固定相填料微粒結合製成
一般厚度為5mm，直徑為47、90mm，吸附劑微粒直徑為5~10μm

全自動化固相萃取系統的獨特優勢

完全自動化萃取操作，操作簡單方便、可輕鬆掌握
可同時處理潔淨和含有大顆粒物的髒污樣品，滿足萃取各種複雜樣品需要
每個樣品每次的處理量可高達4000mL
消除人為誤差，提高數據精確性
可減少操作進行時間、減少萃取所用溶劑量
有利於改善實驗操作人員工作環境
模組化設計：方便用戶隨時將系統擴展升級，控制器能夠同時控制4個SPE-DEX 5000萃取工作站，執行12個樣品萃取程序
具47和90mm不同直徑大小、不同孔徑大小和不同填料SPE萃取膜可供選擇

環檢所公告方法

適用NIEA環檢所公告方法

方法編號	方法名稱
W533.51B	水中鹵乙酸檢測方法－固相萃取濃縮／氣相層析儀／電子捕捉偵測器法
W539.50B	飲用水中微囊藻毒素化學檢測方法－固相萃取與高效液相層析／串聯式質譜儀法
W541.50B	水中壬基酚及雙酚A檢測方法－矽烷衍生化／氣相層析質譜儀法
W542.50B	全氟烷酸類化合物檢測方法－固相萃取與高效液相層析／串聯式質譜儀法
W543.50B	水中抗生素類及鎮痛解熱劑類化合物檢測方法－固相萃取與高效液相層析／串聯式質譜儀法
W544.50B	水中丙烯醯胺檢測方法－固相萃取與高效液相層析／串聯式質譜儀法
W545.50B	水中新興污染物檢測方法－固相萃取與高效液相層析／串聯式質譜儀法
W602.52B	水中多氯聯苯檢測方法－固相萃取／氣相層析儀電子捕捉偵測器法
W603.50B	水中殘留農藥檢測方法－液相層析／串聯式質譜儀法
W610.52B	水中有機磷農藥檢測方法－氣相層析儀／火焰光度偵測器法
W646.50C	水中二刈和巴拉刈檢測方法－固相萃取與高效液相層析／紫外光偵測器法
W656.53B	水中有機磷農藥分析方法－固相萃取／氣相層析儀／火焰光度偵測器或氮、磷偵測器法
W658.51B	水中有機氯農藥分析方法－固相萃取/氣相層析儀/電子捕捉偵測器法
W786.50B	水中五氯硝苯檢測方法－固相萃取／氣相層析電子捕捉偵測器法
W801.53B	水中半揮發性有機化合物檢測方法－氣相層析質譜儀法
W941.51C	自然水體中腐植物質螢光強度檢測方法－II固相萃取法

美國環保署方法與相關應用

相關方法/ 文獻
EPA Method 506：Phthalate and Adipate Esters
EPA Method 508.1：Chlorinated Pesticides, Herbicides, and Organohalides
EPA Method 515.4：Method Detection Limits For EPA Method 515. 4: Chlorinated Acids
EPA Method 526：Selected Semi Volatile Organic Compounds by GC/MS
EPA Method 548.1：Determination of Endothall by Automated SPE
EPA Method 549.2：Determination of Diquat and Paraquat in Drinking Water
EPA Method 552.2：Haloacetic Acid and Dalapon Using the SPE-DEX 4790 Automated Extraction System
Fast Automated SPE and GC/MS Analysis of PAH Compounds in Tap Water Using the SPE-DEX® 4790 Automated Extractor System
Determination of Monocrotophos, Diazinon,Malathion, EPN, and Methamidaphos from Aqueous Samples Using Atlantic HLB SPE Disks

相關方法/ 文獻
EPA Method 608：Determination of Organochlorine Pesticides and PCBs in Wastewater
EPA Method 1657：Determination of Organophosphorous Pesticides in Municipal and Industrial Wastewater
EPA Method 1668A：Chlorinated Biphenyl Congeners by HRGC/HRMS
EPA Method 8015：Total Petroleum Hydrocarbons by GC
EPA Method 8081：Extraction of Organochlorine Pesticides For EPA Method 8081
EPA Method 8141B：Organophosphorus Pesticides by Automated Solid Phase Extraction (SPE): InitialDemonstration of Capability for Selected Compounds
EPA Method 8270D：Determination of Semi-Volatile Organic Compounds in Water Using the Atlantic HLB SPE Disk and Carbon Cartridge
EPA Method 8330B：Determination of Trace Nitroaromatic, Nitroamine, and Nitrate Ester Compounds for
EPA Method 8082A：Application of Automated Solid Phase Extraction for the Determination of Polychlorinated Biphenyls (PCB) in Water
EPA Method 8015B：Method Detection Limits for EPA Method 8015 Total Petroleum Hydrocarbons Using Fully Automated Extraction Equipment
EPA Method 8061A：Determination of Trace Phthalate Ester Compounds for EPA Method 8061A

相關方法/ 文獻
EPA Method 525.3：Determination of Semivolatile Organic Chemicals in Drinking Water
EPA Method 525.2：Determination of Organic Compounds in Drinking Water Using Atlantic C18 SPE Disks
EPA Method 529：Determination of Explosives in Drinking Water by SPE for UCMR2 and EPA Method 529
EPA Method 1694：Determining Pharmaceuticals and Personal Care Products in Aqueous Matrices in Water by Automated Solid Phase Extraction
EPA Method 527：Determination of Selected Pesticides and Flame Retardants in Drinking Water by Solid Phase Extraction for UCMR2 and EPA Method 527
Pharmaceutical and Personal Care Products (PPCPs) Applications
Determination of Endocrine Disrupting Hormones in Drinking and Waste Water
Automated SPE Disk Extraction Method for the Analysis of Nonyl Phenol and Bisphenol A in Water Samples

相關方法/ 文獻
EPA 1664A：Determining Oil and Grease in Seawater by Automated Solid Phase Extraction
EPA 8015B：Determining Diesel and Oil Range Organics in Seawater Using Automated Solid Phase Extraction
EU Standards at IRSA：Determination of PBDEs in River Water Utilizing Automated SPE and Atlantic C18 SPE Disks
Determination of Microcystins in Water Using Automated Solid Phase Extraction and Concentration Techniques.
Determination of Trace Phthalate Ester Compounds in Ground and Surface Water for Global Applications
Determining Poly-Aromatic Hydrocarbons in Seawater Using Automated Solid Phase Extraction
A Dissolved / Particulate Baseline Study of PAH's (Poly-Aromatic Hydrocarbons) in Particulate Laden Water
Turnkey Solutions for the Determination of Total Petroleum Hydrocarbons in Ground and Surface Water Using Automated Solid Phase Extraction
The Determination of Dispersed Oil in Water Using Automated SPE in Compliance with OSPAR and ISO 9377-2 Methods in Norway
Determination of PAHs from Sea Water Using Automated SPE
High Throughput Multi-Residue Screening of Drinking Water using the SPE-DEX and Pegasus GC-TOF MS
Preliminary Method Development for the Analysis of Bentazone in River Water
Determination of Carbaryl in Drinking Water Using Automated SPE and the Atlantic C18 Disk